When the interior of the car gets hot, the car won't start. Well, it will, but it takes a long time and a number of tries. Even if the air outside is fairly cool, if the interior soaks in a lot of sun and gets hot, the car takes forever to start.
If it has more than 1/2 tank of fuel, this is not as likely to happen, but it still does.
Fuel pump relay, maybe?
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